Tetrahedron Letters p. 3399 - 3402 (1984)
Update date:2022-08-05
Topics:
Lee, S. D.
Chan, T. H.
Kwon, K. S.
α-Acyloxyacetates rearrange under LDA conditions to give 2-hydroxy-3-ketoesters.The corresponding trimethylsilyl- or acetyl derivatives can be obtained by quenching the reaction mixture with Me3SiCl or Ac2O.
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