929903-50-4

Basic information

• Product Name: (E)-1,2-diphenylhex-1-en-3-ol
• Synonyms: (E)-1,2-diphenylhex-1-en-3-ol
• CAS NO: 929903-50-4
• Molecular Weight: 252.356
• Mol File: 929903-50-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-1,2-diphenylhex-1-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1,2-diphenylhex-1-en-3-ol(929903-50-4)
• EPA Substance Registry System: (E)-1,2-diphenylhex-1-en-3-ol(929903-50-4)

Safety Data

• Hazardous Substances Data: 929903-50-4(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 123-72-8 butyraldehyde 
• 501-65-5 diphenyl acetylene 
• 13702-35-7 (E)-2,3-diphenyl-propenal 
• 927-77-5 n-propylmagnesium bromide 
• 925-90-6 ethylmagnesium bromide 

Relevant articles and documents

Studies on the zirconium-mediated alkyne-aldehyde coupling reactions: a facile synthesis of stereodefined allylic alcohols and (Z)-2-en-4-yn-1-ols

An improved zirconium-mediated alkyne-aldehyde cross-coupling reaction has been achieved to afford the stereodefined (Z)-allylic alcohols or 3-iodinated allylic alcohols selectively via protonolysis or iodinolysis of the corresponding five-membered oxazirconacycles. This method has also been successfully applied to the synthesis of (Z)-enynols through cross-coupling reactions of three different components involving alkyne, aldehyde, and alkynyl bromide in a one-pot procedure.

Chemoenzymatic dynamic kinetic resolution of allylic alcohols: A highly enantioselective route to acyloin acetates

Dynamic kinetic resolution (DKR) of a series of sterically hindered allylic alcohols has been conducted with Candida antarctica lipase B (CALB) and ruthenium catalyst 1. The optically pure allylic acetates obtained were subjected to oxidative cleavage to