930-39-2

Usage

Uses

Used in Fragrance Industry:
Cyclopropanemethanol, a,a-dimethylis used as a key component in the production of fragrances. Its unique chemical structure contributes to the creation of various scent profiles, enhancing the overall aroma of perfumes, colognes, and other fragrance products.
Used in Chemical Synthesis:
Cyclopropanemethanol, a,a-dimethylserves as a valuable building block in organic synthesis, particularly in the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals. Its ability to undergo various chemical reactions allows chemists to create a wide range of derivatives with specific properties and applications.
Used as a Solvent in Industrial Applications:
Cyclopropanemethanol, a,a-dimethylis utilized as a solvent in certain industrial processes due to its solubility properties. It can dissolve a variety of substances, making it suitable for use in the manufacturing of certain products, such as coatings, adhesives, and elastomers.
Safety Precautions:
While Cyclopropanemethanol, a,a-dimethyloffers numerous applications, it is essential to handle this chemical with caution. Its potential hazards require proper safety measures, including the use of personal protective equipment, proper ventilation, and adherence to safety guidelines to minimize risks during its production, storage, and use.

InChI:InChI=1/C6H12O/c1-6(2,7)5-3-4-5/h5,7H,3-4H2,1-2H3

Upstream product

• 186581-53-3 diazomethane 
• 115-18-4 2-methyl-3-buten-2-ol 
• 3638-35-5 2-cyclopropylpropane 

Downstream Products

• 1003-17-4 2,2-dimethyltetrahydrofuran 
• 4663-22-3 isopropenylcyclopropane 
• 2270-59-9 1-bromo-4-methylpent-3-ene 
• 111833-46-6 4-methylpent-3-en-1-yl benzoate 
• 52278-94-1 2,5-dibromo-2-methylpentane 
• 41182-50-7 5-bromo-2-methyl-1-pentene 
• 172947-13-6 2-cyclopropylpropan-2-amine 
• 19434-65-2 3-chloropropanaldehyde 
• 7712-60-9 5-chloro-2-methyl-pent-2-ene 
• 763-89-3 4-methylpent-3-en-1-ol 
• 58673-35-1 (1-chloro-1-methyl-ethyl)-cyclopropane 
• 191032-91-4 1,4-Dichloro-4-methyl-pentan-3-one 
• 926-56-7 4-methyl-1,3-pentadiene 
• 1462-10-8 4-methyl-1,4-pentanediol 

Relevant academic research and scientific papers

Oxidation of Isopropylcyclopropane by Chromyl Chloride: Ring-Opened Products Support a Hydrogen Atom Abstraction Mechanism

Chromyl chloride (CrO2Cl2) reacts with neat isopropylcyclopropane at 65 °C to give a dark precipitate along with at least 20 organic products. Both cyclopropyl products and ring-opened products are observed: 2-cyclopropyl-2-chloropropane (1,0.4% yield based on chromium), 2-cyclopropyl-2-propanol (2, 0.2%), 5-chloro-2-methyl-2-pentene (3, 0.3%), and 4-methyl-3-penten-1-ol (4, 0.5%) as well as other ring-opened products. Authentic samples of 1-4 were synthesized, and their GC and GC/ MS data were compared with the reaction mixture. Other organic products (5-10) were tentatively assigned by GC/MS on the basis of their m / z and fragmentation patterns. The ratio of (1 + 2) vs (3 + 4) increases by a factor of 2 when the initial concentration of CrO2Cl2 increases from 0.3 to 1.12 M. The reaction was also carried out in the gas phase, and essentially all the products from the liquid phase reaction were observed. The products are explained by a mechanism involving initial hydrogen atom abstraction from the substrate. The resulting dimethylcyclopropylcarbinyl radical can either be trapped by CrO2Cl2 (to form 1 and 2) or ring-open to give 4-methyl-3-pentenyl radical, which reacts with CrO2Cl2 to form 3 and 4 as well as further oxidized products. The oxidation of isopropylcyclopropane by MnO4- in pyridine was also examined. Acetone, an expected ring-opened product, was the only product observed by our analytical techniques. Me2C18O is produced from 18O-labeled MnO4-. These results suggest that the reactions of CrO2Cl2 and MnO4- with isopropylcyclopropane proceed by hydrogen atom transfer to form organic radical intermediates.

Intramolecular trapping of an ylide intermediate in the reaction of1:CH2 with an allylic alcohol

The reaction of 1:CH2, generated by the photolysis of CH2N2, with 2-methyl-3-buten-2-ol leads to the formation of several products including 4-methyl-3-penten-1-ol. This product is best explained as the result of rearrangement of an ylide intermediate.