93007-82-0Relevant academic research and scientific papers
The Reaction of Nitrile Oxide with Organometallic Compounds
Kim, Jae Nyoung,Kim, Hyoung Rae,Ryu, Eung K.
, p. 5117 - 5120 (2007/10/02)
Nitrile oxides react with some organometallic compounds with or without the aid of Lewis acid depending on the organometallic nucleophiles to give oxime derivatives in good yields.
A New Synthesis of Oxime Derivatives from Carbonyl Compounds and N,O-Bis(trimethylsilyl)hydroxylamine
Hoffman, Robert V.,Buntain, Gregory A.
, p. 831 - 833 (2007/10/02)
Reaction of a series of aldehydes and ketones with the potassium salt of N,O-bis(trimethylsilyl)hydroxylamine (2) gave high yields of the corresponding oximate anion 5.This anion, formed in a Peterson-type reaction, could be protonated to the oxime 7 or trapped in situ with a variety of electrophiles to give O-substituted oxime derivatives.
