930597-70-9Relevant academic research and scientific papers
The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water
Lee, Jia Ying,Fan, Wai Yip,Mak, Kar Hang Garvin,Leong, Weng Kee
supporting information, p. 275 - 280 (2013/03/13)
The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally.
[Cp*IrCl2]2-assisted C=C bond cleavage with water: An experimental and computational study
Sridevi, Venugopal Shanmugham,Wai, Yip Fan,Weng, Kee Leong
, p. 1173 - 1177 (2008/10/09)
Reaction of the dimeric species [Cp*IrCl2]2 with a number of organic substrates carrying a terminal alkyne functionality (RCCH) in the presence of water leads to C=C bond cleavage to form Cp*IrCl-(CH2R)(CO). The reaction pathway has been studied both experimentally and computationally.
