930795-32-7

Upstream product

• 994-30-9 triethylsilyl chloride 
• 645394-01-0 (3aR,7aS,4''R)-3-[6'-(2'',2''-dimethyl-[1'',3'']dioxolan-4''-yl)-7-methyl-3-oxo-1,4,5,7a-tetrahydroisobenzofuran-3a-yl]propionitrile 
• 102045-96-5 2,3-O-isopropylidene-L-glyceric acid 
• 60456-21-5 methyl (4S)-2,2-dimethyl-1,3-dioxolane-4-carboxylate 
• 133481-14-8 (2S)-2,3-O-isopropylidene-N-methoxy-N-methylpropanamide 
• 645393-92-6 (4S)-(E)-1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-4-(4-methoxybenzyloxy)-2-methylbut-2-en-1-one 
• 645393-99-3 (3aS,7aS,4'R)-6-(2',2'-dimethyl-[1',3']dioxolan-4'-yl)-7-methyl-3-oxo-1,4,5,7a-tetrahydroisobenzofuran-3a-carbaldehyde 
• 645393-93-7 (4R)-(E)-4-[4-(4-methoxybenzyloxy)-2-methyl-1-methylenebut-2-enyl]-2,2-dimethyl-[1,3]dioxolane 
• 645394-08-7 (3aS,7aS,4'R)-5-(2',2'-dimethyl-[1',3']dioxolan-4'-yl)-7a-hydroxymethyl-4-methyl-3a,6,7,7a-tetrahydro-3H-isobenzofuran-1-one 
• 930795-18-9 (3aR,7aS)-6-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-7-methyl-3-oxo-1,4,5,7a-tetrahydro-isobenzofuran-3a-carboxylic acid 
• 645394-00-9 (3aR,7aS,4''R)-(E)-3-[6'-(2'',2''-dimethyl-[1'',3'']dioxolan-4''-yl)-7-methyl-3-oxo-1,4,5,7a-tetrahydroisobenzofuran-3a-yl]acrylonitrile 
• 645393-94-8 (4'R,7S)-9-(2',2'-dimethyl-[1',3']dioxolan-4'-yl)-7-(4''-methoxybenzyloxymethyl)-3,3,8-trimethyl-2,4-dioxa-spiro[5.5]undec-8-ene-1,5-dione 

Downstream Products

• 930795-33-8 (1'R,2'S,4''R)-3-[4'-(2'',2''-dimethyl-[1'',3'']dioxolan-4''-yl)-3'-methyl-1'-(1'''-hydroxyallyl)-2'-triethylsilanyloxymethylcyclohex-3'-enyl]propionitrile 
• 930795-40-7 (4E)-1-((1R,2S)-1-(2-cyanoethyl)-2-(triethylsilanyloxymethyl)-3-methyl-4-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)cyclohex-3-enyl)-5-((2R,3R,5R)-5-(3-triisopropylsilanyloxypropyl)-3-methyltetrahydrofuran-2-yl)hex-4-enyl acetate 
• 930795-43-0 (4E)-1-((1R,2S)-1-(2-cyanoethyl)-2-ethynyl-3-methyl-4-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)cyclohex-3-enyl)-5-((2R,3R,5R)-5-(3-triisopropylsilanyloxypropyl)-3-methyltetrahydrofuran-2-yl)hex-4-enyl acetate 
• 930795-41-8 (4E)-1-((1R,2S)-1-(2-cyanoethyl)-2-(hydroxymethyl)-3-methyl-4-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)cyclohex-3-enyl)-5-((2R,3R,5R)-5-(3-triisopropylsilanyloxypropyl)-3-methyltetrahydrofuran-2-yl)hex-4-enyl acetate 
• 930795-42-9 acetic acid 1-[1-(2-cyano-ethyl)-4-(2,2-dimethyl-[1,3]dioxolan-4-yl)-2-formyl-3-methyl-cyclohex-3-enyl]-5-[3-methyl-5-(3-triisopropylsilanyloxy-propyl)-tetrahydro-furan-2-yl]-hex-4-enyl ester 
• 930795-39-4 1-((1R,2S)-1-(2-cyanoethyl)-2-(triethylsilanyloxymethyl)-3-methyl-4-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)cyclohex-3-enyl)allyl acetate 

Relevant academic research and scientific papers

Studies on the synthesis of (-)-gymnodimine. Subunit synthesis and coupling

Two principal subunits of the marine algal toxin (-)-gymnodimine were synthesized. A trisubstituted tetrahydrofuran representing C10-C18 of the toxin was prepared via a highly stereoselective iodine-mediated cyclization of an acyclic alkene bearing a bis-