93114-95-5Relevant academic research and scientific papers
CAN (ETHOXYCARBONYL)NITRENE SELECTIVITY BE CONTROLLED BY MICELLAR PSEUDOPHASE?
Bertolaccini, Riccardo,Cerichelli, Giorgio,Loreto, M. Antonietta,Pellacani, Lucio,Tardella, Paolo A.
, p. 587 - 588 (2007/10/02)
The effect of cationic surfactants in the reaction of cyclohexene and (ethoxycarbonyl)nitrene has been studied.When the counter-ion of the surfactant was bromide, the products of bromination of cyclohexene or those requiring the intermediacy of nitrene were observed.The latter were the only products if nitrate was the counter-ion of the surfactant, using N-oxy>urethan, even without added base.
