93125-72-5Relevant academic research and scientific papers
Synthesis of Sugar Nitrates by Nucloephilic Substitution
Afza, Nighat,Malik, Abdul,Latif, Farzana,Voelter, Wolfgang
, p. 1929 - 1934 (2007/10/02)
A rapid high-yielding synthesis of sugar mono- and dinitrates has been achieved via displacement of the trifluoromethylsulfonyloxy (triflate) by the nitrate group.This procedure is mild, convenient, and does not attack highly acid-labile groups.It also do
Classical One Step Syntheses of Mono- and Di-Nitrate Sugars via Triflates
Afza, Nighat,Malik, Abdul,Voelter, Wolfgang
, p. 840 - 842 (2007/10/02)
A new approach for the synthesis of some sugar nitrates is described.The reaction sequence consists of esterifying partially protected carbohydrates with trifluoromethanesulfonic anhydride and reacting the resulting triflates with tetrabutylammonium nitrate.This procedure is mild, convenient and has the advantage of protecting highly acid-labile groups. - Key words: Sugar Nitrates, Triflate Displacement, Tetrabutylammonium Nitrate
