71204-44-9Relevant academic research and scientific papers
A convenient method for the synthesis of cyclic trithiocarbonates on carbohydrate scaffolds
Saeed, Muhammad,Abbas, Muhammad,Abdel-Jalil, Raid J.,Zahid, Muhammad,Voelter, Wolfgang
, p. 315 - 317 (2003)
An efficient regio- and stereoselective method for the synthesis of cyclic trithiocarbonates on carbohydrate skeleton is described. A freshly prepared solution of sodium trithiocarbonate reacts with cis-oriented epoxytriflate pentoses 7-11 to yield the co
Synthesis and properties of selected 4-substituted anhydro sugars
Abdel-Jalil, Raid J.,Saeed, Muhammad,Heeg, Peter,Voelter, Wolfgang
, p. 661 - 666 (2000)
A new class of 4-deoxy-4-([4-substituted-1-piperazinyl], [4-morpholinyl] and [4-(perhydro1,4-thiazin-4-y])])-2,3-anhydrolyxopyranosides (3a-g and 6a-g) were synthesized from epoxy triflate moities 2 and 5 and 4-substituted piperazines, morpholines and perhydro-1,4-thiazines, respectively, to test their antibacterial activity. The characterized series of new compounds was tested in vitro against E. coli ATCC11229, S. aureus ATCC6538 and C. albicans SATCC10231.
Regioselective and Stereoselective Oxirane Ring-Openings of 2,3-Anhydropentopyranosides with Some Methyl Group Donating Organometallic Reagents
Inghardt, Tord,Frejd, Torbjoern,Magnusson, Goeran
, p. 4542 - 4548 (2007/10/02)
By the proper choice of methyl group transferring reagents organometallic (Me4AlLi, Me4AlLi/MeLi (1:1), Me2CuLi, Me3Al, Me2Mg) it is possible to selectively introduce a methyl group into the 2- or 3-position via epoxide ring-opening of four easily availab
A Convenient Synthesis of 4-Amino-4-desoxy Sugars
Malik, Abdul,Roosz, Michael,Voelter, Wolfgang
, p. 559 - 561 (2007/10/02)
Displacement of the triflyl by the amino group in benzyl-2,3-anhydro-4-triflyl-pyranosides 4-6 gives with inversion the benzyl-2,3-anhydro-4-amino-4-desoxypyranosides 7-9.The triflyl group turns out to be a reactive leaving group which can be replaced by
Synthesis of Sugar Nitrates by Nucloephilic Substitution
Afza, Nighat,Malik, Abdul,Latif, Farzana,Voelter, Wolfgang
, p. 1929 - 1934 (2007/10/02)
A rapid high-yielding synthesis of sugar mono- and dinitrates has been achieved via displacement of the trifluoromethylsulfonyloxy (triflate) by the nitrate group.This procedure is mild, convenient, and does not attack highly acid-labile groups.It also do
C-4-Triflate Displacement by Azide in 2,3-Anhydro Sugars; a New Way to 4-Amino-4-deoxy Sugars
Kimmich, Reinhard,Voelter, Wolfgang
, p. 1100 - 1104 (2007/10/02)
Displacement of the triflyl by the azido group in benzyl-2,3-anhydro-4-triflyl-α-D-pyranosides 4-6 gives with inversion the benzyl-2,3-anhydro-4-azido-4-deoxypyranosides 7-9.The triflyl group turns out to be a reactive leaving group which can be replaced
