93126-82-0Relevant academic research and scientific papers
A convenient method for the synthesis of O-tert-butyldimethylsilyl oximes
Ortiz,Cordero,Pinto,Alverio
, p. 409 - 415 (1994)
Aromatic, aliphatic, cyclic and acyclic O-tert-butyldimethylsilyl oximes were prepared in 77 to 85% yield by the reaction of the corresponding aldoximes and ketoximes with tert-butyldimethylchlorosilane (TBSCI) using imidazole/DMF system.
REVERSIBLE 1,4 MIGRATION OF A SILYL GROUP FROM OXYGEN TO CARBON: AN UNEXPECTED ROUTE TO α-TRIALKYLSILYL KETOXIMES
Mora, J.,Costa, A.
, p. 3493 - 3496 (2007/10/02)
Anions generated from trialkylsilyl ethers of methyl ketoximes (1) undergo anionic rearrangement with 1,4 migration of the silyl group.After protonation, the resulting α-trialkylsilyl ketoximes (2), suffer thermal rearrangement with 1,4 migration of the silyl group from carbon to oxygen.
