93126-85-3Relevant academic research and scientific papers
REVERSIBLE 1,4 MIGRATION OF A SILYL GROUP FROM OXYGEN TO CARBON: AN UNEXPECTED ROUTE TO α-TRIALKYLSILYL KETOXIMES
Mora, J.,Costa, A.
, p. 3493 - 3496 (1984)
Anions generated from trialkylsilyl ethers of methyl ketoximes (1) undergo anionic rearrangement with 1,4 migration of the silyl group.After protonation, the resulting α-trialkylsilyl ketoximes (2), suffer thermal rearrangement with 1,4 migration of the silyl group from carbon to oxygen.
