93131-87-4

Basic information

• Product Name: Ethanone, 1-[4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]-
• CAS NO: 93131-87-4
• Molecular Formula: C15H24O2Si
• Molecular Weight: 264.44
• Mol File: 93131-87-4.mol

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]-(93131-87-4)
• EPA Substance Registry System: Ethanone, 1-[4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]-(93131-87-4)

Safety Data

• Hazardous Substances Data: 93131-87-4(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 80463-22-5 4-(1-hydroxyethyl)benzyl alcohol 
• 93184-02-2 1-[4-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-ethanol 

Downstream Products

• 75633-63-5 4-(hydroxymethyl)acetophenone 
• 1421922-87-3 2-bromo-1-[4-({[tert-butyl(dimethyl)silyl]oxy}methyl)phenyl]ethanone 

Relevant articles and documents

Direct synthesis of carbonyl compounds from THP ethers with IBX in the presence of β-cyclodextrin in water

Water, an environmentally friendly reaction medium, has been utilized for the oxidative deprotection of tetrahydropyranyl ethers 1 with IBX at room temperature in the presence of β-cyclodextrin to give the corresponding carbonyl compounds 2.

Pyridinium Fluorochromate or benzyltrimethylammonium Chlorochromate for selective Oxidation of Alcohols.

Selective oxidation of secondary alcohols in the presence of primary ones has been achieved by the following sequences, (1) selective protection of primary alcohols with t-BuMe2SiCl, (2) oxidation of secondary alcohols with title reagents, and (3) deprotection of primary hydroxyls.