93145-01-8

Upstream product

• 109-72-8 n-butyllithium 
• 100033-95-2 N-(phenylselenocarbonyl) piperidine 
• 109-65-9 1-bromo-butane 
• 5351-11-1 1-(butoxyphenylmethyl)piperidine 

Relevant academic research and scientific papers

Generation and reactivity of α-amino-substituted arylmethyllithium organometallics

Reductive cleavage of open chain and cyclic α-N,N-dialkylamino- substituted benzyl alkyl ethers 1a-f with a dispersion of Li metal and a catalytic amount of naphthalene in THF, allowed easy access to a wide array of α-N,N-dialkylamino-substituted benzyllithium derivatives. Reaction of these organometallics with various electrophiles afforded the expected products in satisfactory yields. (C) 2000 Elsevier Science Ltd.

A Novel Deselenation in the Reaction of Selenoamides with Organolithium Reagents

The reaction of selenoamides with organolithium reagents proceeds in a carbophilic manner, and more interestingly, the presence of excess lithium reagents causes a novel deselenation reaction from the carbophilic adducts.