93175-55-4Relevant academic research and scientific papers
REACTION OF ALKENES AND DIENES WITH t-BUTYLMAGNESIUM HALIDES AND ZIRCONOCENE DIHALIDES. A CONVENIENT PROCEDURE FOR HYDROZIRCONATION AND A NOVEL t-BUTYLZIRCONATION OF CONJUGATED ALKENES
Negishi, Ei-ichi,Miller, Joseph A.,Yoshida, Tadao
, p. 3407 - 3410 (1984)
The reaction of nonconjugated monosubstituted alkenes with t-BuMgCl and Cl2ZrCp2 at room temperature produces the corresponding monoalkylzirconium derivatives in high yields, while conjugated alkenes undergo either a novel t-butylzirconation or hydrozirconation depending on the reaction conditions.
