932005-76-0Relevant academic research and scientific papers
Ruthenium-catalyzed synthesis of secondary alkylamines: Selective alkylation with aliphatic amines
Baehn, Sebastian,Hollmann, Dirk,Tillack, Annegret,Bellera, Matthias
, p. 2099 - 2103 (2008)
The chemoselective N-alkylation of tert-alkylamines applying aliphatic amines is described for the first time. In the presence of the Shvo catalyst 1, tert-octylamine 4 and 1-adamantylamine 5 are alkylated using primary, secondary, and even tertiary amine
Borrowing hydrogen methodology for amine synthesis under solvent-free microwave conditions
Watson, Andrew J. A.,Maxwell, Aoife C.,Williams, Jonathan M. J.
supporting information; experimental part, p. 2328 - 2331 (2011/05/17)
Application of microwave heating to the Borrowing Hydrogen strategy to form C-N bonds from alcohols and amines is presented, removing the need for solvent and reducing the reaction times while still yielding results comparable with those using thermal heating.
