93296-15-2Relevant academic research and scientific papers
Enantioselective 1,4-additions of ClMeAl(CHCHR) (R = alkyl, alkenyl, Ph) to cyclohexenones
Willcox,Woodward,Alexakis
supporting information, p. 1655 - 1657 (2014/02/14)
Chloromethylvinyl alanes (E)-ClMeAl(CH=CHR) prepared directly from terminal alkynes undergo 1,4-addition to cyclohexenone and 3-methylcyclohexenone in moderate to good yield (30-70%) and good to excellent stereoselectivity (80-98% ee) using readily availa
