93321-12-1

Basic information

• Product Name: 2-(2'-methoxyphenyl)naphthalene
• Synonyms: 2-(2'-methoxyphenyl)naphthalene
• CAS NO: 93321-12-1
• Molecular Weight: 234.298
• Mol File: 93321-12-1.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: 2-(2'-methoxyphenyl)naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2'-methoxyphenyl)naphthalene(93321-12-1)
• EPA Substance Registry System: 2-(2'-methoxyphenyl)naphthalene(93321-12-1)

Safety Data

• Hazardous Substances Data: 93321-12-1(Hazardous Substances Data)

Upstream product

• 578-57-4 2-bromoanisole 
• 530-93-8 1,2,3,4-tetrahydronaphthalen-2-one 
• 766-51-8 2-Chloroanisole 
• 21473-01-8 2-naphthalenylmagnesium bromide 
• 32316-92-0 naphthalene-2-boronic acid 
• 529-28-2 4-iodoanisol 
• 13922-41-3 1-Naphthylboronic acid 
• 20176-11-8 2-naphthalene carboxylic anhydride 
• 5720-06-9 2-Methoxyphenylboronic acid 
• 91-23-6 2-Nitroanisole 
• 15300-41-1 (naphthalen-2-yl)dimethylcarbamate 
• 376353-52-5 (2-methoxyphenyl)triethoxysilane 
• 573-57-9 1,4-dihydronaphthalene-1,4-epoxide 
• 4731-65-1 tris(o-methoxyphenyl)phosphine 

Downstream Products

• 1400967-87-4 C₁₆H₁₁⁽²⁾HO 
• 239-30-5 benzo[b]naphtho[2,1-d]furan 
• 1400967-84-1 5a,6-dihydrobenzo[d]naphtho[2,3-b]furan 
• 1400967-85-2 5,11a-dihydrobenzo[d]naphtho[1,2-b]furan 
• 78210-35-2 2-(2-hydroxyphenyl)naphthalene 

Relevant articles and documents

Microwave irradiation as a high-speed tool for activation of sluggish aryl chlorides in Grignard reactions

Grignard reagents have been generated from reluctant aryl chlorides and bromides using controlled microwave heating to establish a safe, productive and reproducible method. In the synthesis of a novel HIV-1 protease inhibitor, microwave irradiation was both used to generate the starting arylmagnesium halide and to promote a subsequent Kumada coupling. Georg Thieme Verlag Stuttgart.

Highly active and reusable hydrotalcite-supported Pd(0) catalyst for Suzuki coupling reactions of aryl bromides and chlorides

A palladium(0) nanocluster supported on hydrotalcite has been prepared and tested for the Suzuki coupling reaction. The prepared catalyst showed very efficient catalytic activity for cross coupling of iodo- and bromoarenes under very mild reaction conditions, affording >90% yield. Under the optimized reaction conditions, chloroarenenes also showed very good reactivity. Transmission electron microscopic imaging data showed the formation of very small Pd(0)-nanoclusters (d = 2.2 ± 0.5 nm) well dispersed on the support, which enhanced the activity and stability of the catalyst for the Suzuki cross-coupling reaction. This catalytic system offers an easy method of preparation with good activity and reusability up to five cycles.

Nickel- or Iron-Catalyzed Cross-Coupling of Aryl Carbamates with Arylsilanes

Aryl carbamates were for the first time applied as electrophiles in the cross-coupling with arylsilanes via nickel or iron catalysis to construct valuable biaryl compounds. This new coupling reaction features a good group tolerance and non-sensitivity to steric hindrance on both aryl carbamates and arylsilanes. (Figure presented.).