933456-78-1

Basic information

• Product Name: N-[(1R,2R)-2-(diMethylaMino)cyclohexyl]-N'-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-Thiourea
• Synonyms: N-[(1R,2R)-2-(diMethylaMino)cyclohexyl]-N'-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-Thiourea;N-[(1R,2R)-2-(Dimethylamino)cyclohexyl]-N'-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)thiourea,99%d.e.
• CAS NO: 933456-78-1
• Molecular Formula: C23H37N3O9S
• Molecular Weight: 531.61958
• Mol File: 933456-78-1.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-[(1R,2R)-2-(diMethylaMino)cyclohexyl]-N'-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-Thiourea(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(1R,2R)-2-(diMethylaMino)cyclohexyl]-N'-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-Thiourea(933456-78-1)
• EPA Substance Registry System: N-[(1R,2R)-2-(diMethylaMino)cyclohexyl]-N'-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-Thiourea(933456-78-1)

Safety Data

• Hazardous Substances Data: 933456-78-1(Hazardous Substances Data)

Upstream product

• 894493-95-9 (1S,2S)-N,N-dimethylcyclohexane-1,2-diamine 
• 14152-97-7 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate 
• 320778-92-5 (1R,2R)-N,N-dimethylcyclohexane-1,2-diamine 
• 14152-97-7 2,3,4,6-tetra-O-Acetyl-β-D-galactopyranosyl isothiocyanate 

Relevant articles and documents

Highly enantioselective Michael addition of malonates to nitroolefins catalyzed by chiral bifunctional tertiary amine-thioureas based on saccharides

A series of saccharide-derived bifunctional tertiary amine-thioureas for the asymmetric Michael addition reaction have been designed and synthesized. The addition products between malonates and various nitroolefins were obtained in high yields (up to 99%)

Sugar-derived bifunctional thiourea organocatalyzed asymmetric Michael addition of acetylacetone to nitroolefins

A bifunctional chiral thiourea organocatalyst bearing a glycosyl scaffold and a tertiary amino group proved to be an effective organocatalyst for the asymmetric Michael addition of acetylacetone to nitroolefins. The corresponding adducts were obtained in