93347-32-1Relevant academic research and scientific papers
INDENYL AND FLUORORENYL TRANSITION METAL COMPLEXES X. ANIONIC CHROMIUM TRICARBONYL COMPLEXES OF FLUORADENE, SUBSTITUTED FLUORENES AND INDENE: THE STRUCTURE OF ION PAIRS AND η6->η5 REARRANGEMENTS
Ustynyuk, N. A.,Oprunenko, Yu. F.,Malyugina, S. G.,Trifonova, O. I.,Ustynyuk, Yu. A.
, p. 185 - 200 (1984)
The metallotropic η6 η5 tautomeric equilibrium in anionic chromium tricarbonyl complexes of fluoradene, substituted fluorenes and indene has been studied.A criterion is proposed for determining the ion-pair type in η6-anions according to the E-band splitting in the ν(CO) region of their IR spectra.The influence of ligand structure and cation solavtion on Keq. is discussed.
