Journal of Organometallic Chemistry p. 185 - 200 (1984)
Update date:2022-08-04
Topics:
Ustynyuk, N. A.
Oprunenko, Yu. F.
Malyugina, S. G.
Trifonova, O. I.
Ustynyuk, Yu. A.
The metallotropic η6 <*> η5 tautomeric equilibrium in anionic chromium tricarbonyl complexes of fluoradene, substituted fluorenes and indene has been studied.A criterion is proposed for determining the ion-pair type in η6-anions according to the E-band splitting in the ν(CO) region of their IR spectra.The influence of ligand structure and cation solavtion on Keq. is discussed.
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