INDENYL AND FLUORORENYL TRANSITION METAL COMPLEXES X. ANIONIC CHROMIUM TRICARBONYL COMPLEXES OF FLUORADENE, SUBSTITUTED FLUORENES AND INDENE: THE STRUCTURE OF ION PAIRS AND η6->η5 REARRANGEMENTS

DOI: 10.1016/0022-328X(84)80359-9

Source and publish data:

Journal of Organometallic Chemistry p. 185 - 200 (1984)

Update date:2022-08-04

Topics:

Authors:

Ustynyuk, N. A.

Oprunenko, Yu. F.

Malyugina, S. G.

Trifonova, O. I.

Ustynyuk, Yu. A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(84)80359-9

The metallotropic η⁶ <*> η⁵ tautomeric equilibrium in anionic chromium tricarbonyl complexes of fluoradene, substituted fluorenes and indene has been studied.A criterion is proposed for determining the ion-pair type in η⁶-anions according to the E-band splitting in the ν(CO) region of their IR spectra.The influence of ligand structure and cation solavtion on K_eq. is discussed.

Full text of DOI:10.1016/0022-328X(84)80359-9

Products guided by the article

Product name:(η6-methyltriphenylmethane)chromium tricarbonyl

Cas No:93347-32-1

R&D Labs maybe for 93347-32-1

Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA
Hangzhou Taiyan Trading Co., Ltd(expird)

Contact:+86-13777583958

Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Jinan Jinguilin Chemical Co.,Ltd

Contact:+86-531-81188412

Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan

Relevant to this article

Ribose-modified mizoribine analogues: Synthesis and biological evaluation

Doi:10.1080/15257770500334673
(2005)
SYNTHESIS OF BIS-PENTAFLUOROTELLURIUMOXIDE FLUOROCARBONS

Doi:10.1016/S0022-1139(00)85115-5
(1984)
Tetrasubstituted pyrrolidines via a tandem aza-Payne/hydroamination reaction

Doi:10.1021/ja068077w
(2007)
A new molecular scaffold for the formation of supramolecular peptide double helices: The crystallographic insight

Doi:10.1021/ol0701870
(2007)
Axially dissymmetric binaphthyldiimine chiral Salen-type ligands for catalytic asymmetric addition of diethylzinc to aldehyde

Doi:10.1016/S0957-4166(02)00571-2
(2002)
Synthesis and optical properties of a new triphenylamine-p-phenylenevinylene-small molecule with applications in high open-circuit voltage organic solar cells

Doi:10.1039/c5nj01525a
(2015)

Article Doi