93398-04-0

Basic information

• Product Name: Benzenamine, N-butyl-2-methoxy-4-nitro-
• CAS NO: 93398-04-0
• Molecular Formula: C11H16N2O3
• Molecular Weight: 224.26
• Mol File: 93398-04-0.mol

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-butyl-2-methoxy-4-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-butyl-2-methoxy-4-nitro-(93398-04-0)
• EPA Substance Registry System: Benzenamine, N-butyl-2-methoxy-4-nitro-(93398-04-0)

Safety Data

• Hazardous Substances Data: 93398-04-0(Hazardous Substances Data)

Upstream product

• 709-09-1 3,4-dimethoxynitrobenzene 
• 109-73-9 N-butylamine 

Relevant articles and documents

PHOTOREACTION OF 3,4-DIMETHOXY-1-NITROBENZENE WITH BUTYLAMINE. A pH DEPENDENCE OF REGIOSELECTIVITY

Irradiation of 3,4-dimethoxy-1-nitrobenzene in the presence of butylamine leads to the formation of both possible photosubstitution products, i.e., 2-methoxy-4-nitro-N-butylaniline and 2-methoxy-5-nitro-N-butylaniline with the predominance of the latter.Regioselectivity of the reaction as measured by molar ratio of the two isomeric products varies with pH of the solution, ranging from 3:1 at pH 10 to 12:1 at pH 12.The results are discussed in view of possible use of 3,4-dimethoxy-1-nitrobenzene moiety as a lysine-directed photoaffinity probe.

NITROPHENYL ETHERS AS POSSIBLE PHOTOAFFINITY LABELS. THE NUCLEOPHILIC AROMATIC PHOTOSUBSTITUTION REVISITED.

The photoreactions of nitrophenyl ethers with simple primary and secondary amines show a remarkable nucleophile influence on the reaction orientation.Calculations indicate a change from charge controlled to frontier orbital controlled reactions moving from smaller to larger amines.