93414-74-5

Upstream product

• 621-23-8 1,2,3-trimethoxybenzene 
• 220662-80-6 2-{[(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)oxy]methyl}benzoic acid 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 100-39-0 benzyl bromide 
• 74352-41-3 2-Pyridyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 688800-59-1 2-((2R,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxymethyl)-benzoic acid benzyl ester 
• 365535-55-3 2'-(benzyloxycarbonyl)benzyl β-D-glucopyranoside 

Downstream Products

• 73244-61-8 α-1-deoxy-1-(2',4',6'-trimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose 
• 73244-62-9 (2R,3S,4R,5R,6R)-2-Hydroxymethyl-6-(2,4,6-trimethoxy-phenyl)-tetrahydro-pyran-3,4,5-triol 

Relevant academic research and scientific papers

2′-Carboxybenzyl glycosides: glycosyl donors for C-glycosylation and conversion into other glycosyl donors

Glycosylation of various glycosyl acceptors with 2′-carboxybenzyl (CB) 2,3,4,6-tetra-O-benzyl-β-d-glucopyranoside and CB 2,3,4,6-tetra-O-benzyl-α-d-mannopyranoside as glycosyl donors afforded α-C-glycosides exclusively or predominantly in good yields. CB

C-GLYCOSIDATION OF PYRIDYL THIOGLYCOSIDES

The pyridylthioglycosides 1 are efficiently transformed into the corresponding C-glycosides via reaction with silver(I) triflate and a variety of carbon nucleophiles.