934219-75-7

Upstream product

• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 934219-70-2 (4S,5S)-5-(3,4-dimethoxyphenyl)-5-(triisopropylsilyloxy)-4-(trityloxymethyl)pentanoic acid 
• 934219-69-9 (5S,6S)-6-(3,4-dimethoxyphenyl)-6-(triisopropylsilyloxy)-5-trityloxymethyl-1-hexene 
• 934219-68-8 (S)-2-[(S)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]-5-hexen-1-ol 
• 934219-74-6 (S)-2-[(2S,3S)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-pentenal 
• 89980-69-8 3,4-dimethoxyphenylmagnesium bromide 
• 934219-67-7 (S)-4-benzyl-3-{(R)-2-[(S)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]-5-hexenoyl}-2-oxazolidinone 
• 934219-66-6 (S)-4-benzyl-3-{(R)-2-[(S)-(hydroxy)(3,4-dimethoxyphenyl)methyl]-5-hexenoyl}-2-oxazolidinone 
• 934219-73-5 (S)-2-[(2S,3S)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-penten-1-ol 
• 934219-72-4 (S)-4-benzyl-3-{(S)-2-[(2S,3S)-3-(3,4-dimethoxyphenyl)-3-(triisopropylsilyloxy)-2-(trityloxymethyl)prop-1-yl]-4-pentenoyl}-2-oxazolidinone 
• 934219-71-3 (S)-4-benzyl-3-[(4S,5S)-5-(3,4-dimethoxyphenyl)-5-(triisopropylsilyloxy)-4-(trityloxymethyl)pentanoyl]-2-oxazolidinone 

Downstream Products

• 934219-76-8 (1R,2S,4S)-2-allyl-5-hydroxy-1-(3,4-dimethoxyphenyl)-4-[(S)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]pentyl acetate 
• 934219-77-9 (1S,2S,4S)-2-allyl-5-hydroxy-1-(3,4-dimethoxyphenyl)-4-[(S)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]pentyl acetate 
• 934219-79-1 (2S,3S,5S)-3-allyl-2-(3,4-dimethoxyphenyl)-5-[(S)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]tetrahydropyran 
• 934219-80-4 (2S,3S,5S)-3-(3,4-dimethoxycinnamyl)-2-(3,4-dimethoxyphenyl)-5-[(S)-(3,4-dimethoxyphenyl)(triisopropylsilyloxy)methyl]tetrahydropyran 

Relevant academic research and scientific papers

Determination of the stereochemistry of the tetrahydropyran sesquineolignans morinols A and B

The 7′,8′-stereochemistry of the tetrahydropyran sesquineolignans morinols A and B was determined as threo via synthetic studies and by comparison of NMR data of 7′,8′-threo-morinol and 7′,8′-erythro-morinol. This study also confirmed that the biosynthetic process produces enantiomeric mixtures of morinols A and B. This was ascertained by comparing the specific rotations of synthesized morinols A and B with those of naturally occurring morinols A and B.