934243-06-8

Basic information

• Product Name: (+)-(3S,1E)-[dimethyl-(3-methyl-oct-1-enyl)phenyl]silane
• Synonyms: (+)-(3S,1E)-[dimethyl-(3-methyl-oct-1-enyl)phenyl]silane
• CAS NO: 934243-06-8
• Molecular Weight: 260.495
• Mol File: 934243-06-8.mol

Chemical Properties

• CAS DataBase Reference: (+)-(3S,1E)-[dimethyl-(3-methyl-oct-1-enyl)phenyl]silane(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(3S,1E)-[dimethyl-(3-methyl-oct-1-enyl)phenyl]silane(934243-06-8)
• EPA Substance Registry System: (+)-(3S,1E)-[dimethyl-(3-methyl-oct-1-enyl)phenyl]silane(934243-06-8)

Safety Data

• Hazardous Substances Data: 934243-06-8(Hazardous Substances Data)

Upstream product

• 934242-94-1 (-)-(1R,2Z)-1-[dimethyl(phenyl)silanyl]-oct-2-enyl pentafluorobenzoate 
• 544-97-8 dimethyl zinc(II) 
• 123-73-9 trans-Crotonaldehyde 
• 768-33-2 phenyldimethylsilyl chloride 
• 308796-10-3 (1-pentyl)zinc(II) bromide 
• 110-53-2 1-Bromopentane 
• 1846-68-0 oct-2-ynal 
• 934242-96-3 1-[dimethyl(phenyl)silanyl]oct-2-yn-1-one 
• 934242-95-2 1-[dimethyl(phenyl)silanyl]oct-2-yn-1-ol 

Downstream Products

• 934243-21-7 ethyl (+)-(3S,1E)-4-(3-methyloct-1-enyl)benzoate 
• 934243-22-8 (+)-(3S,1E)-(3-methyloct-1-enyl)benzene 

Relevant articles and documents

Enantio- and Regioconvergent Nickel-Catalyzed C(sp3)?C(sp3) Cross-Coupling of Allylic Electrophiles Steered by a Silyl Group

A two-step sequence for the enantio- and diastereoselective synthesis of exclusively alkyl-substituted acyclic allylic systems with a stereocenter in the allylic position is reported. The asymmetric induction and the site selectivity are controlled in an

Highly diastereoselective preparation of (E)-alkenylsilanes bearing an α-chiral center

(Chemical Equation Presented) The copper(I)-mediated anti-S N2′ allylic substitution allows a highly stereoselective preparation of alkenylsilanes bearing a chiral center in the α-position with high transfer of chirality. These alkenylsilanes were converted into α,β-unsaturated ketones or into the corresponding boronic esters without loss of the chiral information.