934586-53-5

Basic information

• Product Name: methyl 2-diazo-3-(3-(2-methoxy-2-oxoethyl)-2-oxo-1-(2-(1-tosyl-1H-indol-3-yl)acetyl)piperidin-3-yl)-3-oxo-propanoate
• Synonyms: methyl 2-diazo-3-(3-(2-methoxy-2-oxoethyl)-2-oxo-1-(2-(1-tosyl-1H-indol-3-yl)acetyl)piperidin-3-yl)-3-oxo-propanoate
• CAS NO: 934586-53-5
• Molecular Weight: 608.629
• Mol File: 934586-53-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2-diazo-3-(3-(2-methoxy-2-oxoethyl)-2-oxo-1-(2-(1-tosyl-1H-indol-3-yl)acetyl)piperidin-3-yl)-3-oxo-propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-diazo-3-(3-(2-methoxy-2-oxoethyl)-2-oxo-1-(2-(1-tosyl-1H-indol-3-yl)acetyl)piperidin-3-yl)-3-oxo-propanoate(934586-53-5)
• EPA Substance Registry System: methyl 2-diazo-3-(3-(2-methoxy-2-oxoethyl)-2-oxo-1-(2-(1-tosyl-1H-indol-3-yl)acetyl)piperidin-3-yl)-3-oxo-propanoate(934586-53-5)

Safety Data

• Hazardous Substances Data: 934586-53-5(Hazardous Substances Data)

Upstream product

• 128742-77-8 [N-(p-toluenesulfonyl)indol-3-yl]acetic acid 
• 3731-16-6 3-carboethoxy-2-pyridone 
• 915706-91-1 2-(1-tosyl-1H-indol-3-yl)acetyl chloride 
• 915707-12-9 methyl 3-(3-(2-methoxy-2-oxoethyl)-2-oxo-piperidin-3-yl)-3-oxo-propanoate 
• 908003-71-4 3-(3-tert-butoxycarbonylmethyl-2-oxo-piperidin-3-yl)-3-oxo-propionic acid methyl ester 
• 908003-70-3 3-tert-butoxycarbonylmethyl-2-oxo-piperidine-3-carboxylic acid ethyl ester 
• 908003-82-7 3-{[(tert-butoxy)carbonyl]methyl}-2-oxopiperidine-3-carboxylic acid 
• 934586-58-0 methyl 3-(3-(2-methoxy-2-oxoethyl)-2-oxo-1-(2-(1-tosyl-1H-indol-3-yl)acetyl)piperidin-3-yl)-3-oxo-propanoate 

Relevant articles and documents

Cycloaddition protocol for the assembly of the hexacyclic framework associated with the kopsifoline alkaloids

(Chemical Equation Presented) An approach to the hexacyclic framework of the kopsifoline alkaloids has been developed and is based on a Rh(II)-catalyzed cyclization-cycloaddition cascade. The resulting [3+2]-cycloadduct was readily converted into the TBS

Rhodium carbenoid induced cycloadditions of diazo ketoimides across indolyl π-bonds

A series of diazo ketoimides prepared from (1H-indol-3-yl)acetyl chloride and alkyl 2-diazo-3-(3-substituted-2-oxopiperidin-3-yl)-3-oxopropanoates were treated with rhodium(II) acetate. Attack of the imido carbonyl oxygen at the resultant rhodium carbenoi