93472-46-9Relevant academic research and scientific papers
Realized C-H functionalization of aryldiazo compounds via rhodium relay catalysis
Qiu, Lin,Huang, Daorui,Xu, Guangyang,Dai, Zhenya,Sun, Jiangtao
, p. 1810 - 1813 (2015)
An unprecedented C-H functionalization of aryldiazo compounds without a preinstallation of directing group has been realized under mild conditions, which differs from former reports in its use of diazo compounds as coupling partners in directed C-H activations. This novel transformation has been realized by a rhodium self-relay catalysis, a tandem process of the in situ formation of a directing group and sequential C-H bond activation.
ISOQUINOLINE DERIVATIVES FROM THE RITTER-TYPE REACTION OF VINYL CATIONS
Kitamura, Tsugio,Kobayashi, Shinjiro,Taniguchi, Hiroshi
, p. 1351 - 1354 (2007/10/02)
Both silver-assisted reaction of β-arylvinyl bromides and the photolysis in nitriles gave isoquinoline derivatives, indicating that the Ritter reaction involving a vinyl cation took place.
