25354-48-7

Upstream product

• 2592-73-6 1,1-dibromo-2,2-diphenylethylene 
• 5720-07-0 4-methoxyphenylboronic acid 
• 824-94-2 p-methoxybenzyl chloride 
• 18648-74-3 2,2-diphenyl-1-(4-methoxyphenyl)ethylene 
• 19838-89-2 2-(4-methoxyphenyl)-1,1-diphenylethan-1-ol 
• 7726-95-6 bromine 
• 64-19-7 acetic acid 
• 1889-74-3 1-(4-methoxyphenyl)-2,2-diphenylethanone 

Downstream Products

• 122127-43-9 1-(p-methoxyphenyl)-2,2-diphenyl-1-propoxyethene 
• 1889-74-3 1-(4-methoxyphenyl)-2,2-diphenylethanone 
• 4873-38-5 4'-hydroxy-2,2-diphenylacetophenone 
• 121410-90-0 1-bromo-1-(p-ethoxyphenyl)-2,2-diphenylethene 
• 128191-31-1 4'-ethoxy-2,2-diphenylacetophenone 
• 18648-74-3 2,2-diphenyl-1-(4-methoxyphenyl)ethylene 
• 122127-42-8 1-ethoxy-1-(p-methoxyphenyl)-2,2-diphenylethene 
• 122127-48-4 1-(p-methoxyphenyl)-2,2-diphenyl-1-(2-propoxy)ethene 
• 92901-79-6 5,5-dimethyl-2,2-diphenyl-4-(p-methoxyphenyl)-3-oxazoline 
• 93472-44-7 3-(4-methoxyphenyl)-1-methyl-4-phenylisoquinoline 
• 73514-71-3 (3R,4R)-5-(4-Methoxy-phenyl)-2,2-diphenyl-3,4-dihydro-2H-pyrrole-3,4-dicarboxylic acid dimethyl ester 
• 1394025-14-9 C₄₇H₃₇NO₂ 
• 1394025-16-1 C₅₉H₄₅NO₂ 
• 1394025-02-5 2-[1-(4-methoxyphenyl)-2,2-diphenylvinyl]-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 

Relevant academic research and scientific papers

Synthesis of Multisubstituted Triphenylenes and Phenanthrenes by Cascade Reaction of o-Iodobiphenyls or (Z)-β-Halostyrenes with o-Bromobenzyl Alcohols through Two Sequential C-C Bond Formations Catalyzed by a Palladium Complex

o-Bromobenzyl alcohol has been developed as a novel annulating reagent, bearing both nucleophilic and electrophilic substituents, for the facile synthesis of polycyclic aromatic hydrocarbons. A palladium/electron-deficient phosphine catalyst efficiently coupled o-iodobiphenyls or (Z)-β-halostyrenes with o-bromobenzyl alcohols to afford triphenylenes and phenanthrenes, respectively. The present cascade reaction proceeded through deacetonative cross-coupling and sequential intramolecular cyclization. An array of experimental data suggest that the reaction mechanism involves the equilibrium of 1,4-palladium migration.

Pyridine-cored V-shaped π-conjugated oligomers: Synthesis and optical properties

A new series of V-shaped pyridine-cored π-conjugated oligomers are synthesized utilizing two-fold Heck/Suzuki coupling reactions. Optical properties of these compounds (λmax=390-449 nm, Φfl=79-5%, in solutions) are discussed. They are shown to be thermally stable and soluble in common organic solvents. Stilbenoid oligomers exhibited much higher fluorescence quantum yields than tri- and tetra-phenylethylene substituted oligomers in solutions.

Palladium-catalysed direct synthesis of benzo[b]thiophenes from thioenols

The one-pot conversion of thioenols into benzo[b]thiophenes was achieved by using a simple palladium catalyst such as PdCl2 or PdCl 2(cod). The Royal Society of Chemistry.

Stability-reactivity relation on the reaction of β,β-disubstituted vinyl cations with ethanol

A family of β,β-disubstituted α-(p-methoxyphenyl)vinyl cations has been generated by the laser flash photolysis of the corresponding vinyl bromides, and the rates of reactions of the cations with ethanol in acetonitrile have been measured at 25°C. The obs