93512-05-1

Basic information

• Product Name: 2-Cyclohexene-1-carboxylic acid, 1-(3-chloropropyl)-2-(trimethylstannyl)-, methyl ester
• CAS NO: 93512-05-1
• Molecular Formula: C14H25ClO2Sn
• Molecular Weight: 379.514
• Mol File: 93512-05-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexene-1-carboxylic acid, 1-(3-chloropropyl)-2-(trimethylstannyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexene-1-carboxylic acid, 1-(3-chloropropyl)-2-(trimethylstannyl)-, methyl ester(93512-05-1)
• EPA Substance Registry System: 2-Cyclohexene-1-carboxylic acid, 1-(3-chloropropyl)-2-(trimethylstannyl)-, methyl ester(93512-05-1)

Safety Data

• Hazardous Substances Data: 93512-05-1(Hazardous Substances Data)

Upstream product

• 93493-97-1 methyl 2-(trimethylstannyl)-1-cyclohexenecarboxylate 
• 6940-76-7 1-iodo-3-chloro-propane 
• 4111-54-0 lithium diisopropyl amide 

Downstream Products

• 152564-14-2 3-(3-chloropropyl)-3-(hydroxymethyl)-2-(trimethylstannyl)-2-cyclohexene 

Relevant articles and documents

A new annulation method. Total syntheses of the sesquiterpenoids (+/-)-chiloscyphone and (+/-)-6-epi-chiloscyphone

The efficacy of a new annulation method, developed for the construction of functionalized bicyclic compounds, is illustrated by conversion of the β-keto esters 18 and 19 into the bicyclonon-1-enes 33 and 34, respectively, and by transformation of 2-methoxycarbonylcyclopentanone (20) into the bicyclonon-6-ene 38 and the bicyclodec-7-enes 48 and 51.Application of the method to total syntheses of the structurally unusual sesquiterpenoids (+/-)-chiloscyphone (16) and (+/-)-6-epi-chiloscyphone (17) is described.