93550-89-1Relevant academic research and scientific papers
1,1-Dihalogenocyclopropanes Derived from Terpenes. The Stereochemistry of Cyclopropylidene Insertion into Carbon-Hydrogen Bonds Adjacent to Alcohols
Baird, Mark S.,Buxton, Sheila R.,Sadler, Peter
, p. 1379 - 1385 (2007/10/02)
Treatment of the alcohol (13) with methyl-lithium in ether leads to the ketone (5), whereas (12) gives no ketone and the major product is the alcohol (16).The formation of (5) from (13) establishes the requirement for a syn-relationship between a C-H bond at the 1-position and C-2' in the conversion of 1-(2',2'-dibromocyclopropyl)alkan-1-ols into (cyclopropyl)alkyl ketones.
