935510-48-8

Basic information

• Product Name: C₂₂H₃₆O₂NO₂NO₂
• Synonyms: C₂₂H₃₆O₂NO₂NO₂
• CAS NO: 935510-48-8
• Molecular Weight: 424.538
• Mol File: 935510-48-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₂H₃₆O₂NO₂NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₃₆O₂NO₂NO₂(935510-48-8)
• EPA Substance Registry System: C₂₂H₃₆O₂NO₂NO₂(935510-48-8)

Safety Data

• Hazardous Substances Data: 935510-48-8(Hazardous Substances Data)

Upstream product

• 111-83-1 1-bromo-octane 
• 123-31-9 hydroquinone 
• 67399-94-4 1,4-bis(octyloxy)benzene 

Downstream Products

• 935510-49-9 C₂₂H₃₆O₂NH₂NH₂ 
• 935510-50-2 C₅₃H₈₄N₄O₇ 

Relevant articles and documents

Dynamic [2]catenanes based on a hydrogen bonding-mediated bis-zinc porphyrin foldamer tweezer: A case study

(Chemical Equation Presented) This paper describes the self-assembly of a new class of three-component dynamic [2]catenanes, which are driven or stabilized by intramolecular hydrogen bonding, coordination, and electrostatic interaction. One of the component molecules 2, consisting of an aromatic oligoamide spacer and two peripheral zinc porphyrin units, was designed to adopt a folded preorganized conformation, which is stabilized by consecutive intramolecular three-centered hydrogen bonds. Component molecule 3 is a linear secondary ammonium bearing two peripheral pyridine units, which was designed to form a 1:1 complex with 24-crown-8 (5). The 1H NMR and UV-vis experiments in CDCl3-CD3CN (4:1 v/v) revealed that, due to the preorganized U-shaped feature, 2 could efficiently bind 3 through the cooperative zinc-pyridine coordination to generate highly stable 1:1 complex 2·3. Adding 5 to the 1:1 solution of 2 and 3 led to the formation of dynamic three-component [2]catenane 2·3·5 as a result of the threading of 3 through 5. 1H NMR studies indicated that in the 1:1:1 solution (3 mM) [2]catenane 2·3·5 was generated in 55% yield at 25°C. The yield was increased with the reduction of the temperature and [2]catenane could be produced quantitatively in a 1:1:2 solution ([2] = 3 mM) at -13°C. Replacing 3 with 1,2-bis(4,4′-bipyridinium)ethane (4) in the three-component solution could also give rise to similar dynamic [2]-catenane 2·4·5 albeit in slightly lower yield.