67399-94-4

Basic information

• Product Name: 1,2-(DIOCTYLOXY)BENZENE
• Synonyms: 1,2-BIS(OCTYLOXY)BENZENE;1,2-(DIOCTYLOXY)BENZENE;1,2-(Dioctyloxy)benzene,98%;1,4-BIS(OCTYLOXY)BENZENE;1,4-dioctoxybenzene
• CAS NO: 67399-94-4
• Molecular Formula: C₂₂H₃₈O₂
• Molecular Weight: 334.54
• Mol File: 67399-94-4.mol
• Article Data: 52

Chemical Properties

• Melting Point: 56-59 °C(lit.)
• Boiling Point: 332-333 °C(lit.)
• Flash Point: 187 °F
• Appearance: /
• Density: 0.904 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.4840(lit.)
• CAS DataBase Reference: 1,2-(DIOCTYLOXY)BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-(DIOCTYLOXY)BENZENE(67399-94-4)
• EPA Substance Registry System: 1,2-(DIOCTYLOXY)BENZENE(67399-94-4)

Safety Data

• Safety Statements: 24/25
• WGK Germany: 3
• Hazardous Substances Data: 67399-94-4(Hazardous Substances Data)

Usage

Chemical Properties

white low melting needles

Uses

1,4-Bis(octyloxy)benzene is a reagent used in the preparation of semiconducting polymers containing pyrimidines.

Upstream product

• 111-83-1 1-bromo-octane 
• 106-51-4 p-benzoquinone 
• 108-86-1 bromobenzene 
• 474450-89-0 1,4-dimagnesiobromo-2,5-dioctylbenzene 
• 111-25-1 1-bromo-hexane 
• 123-31-9 hydroquinone 
• 111-87-5 octanol 
• 108-46-3 recorcinol 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 442911-57-1 1,4-bis(octyloxy)benzene-2-boronic acid 
• 111-85-3 n-chlorooctane 
• 629-27-6 1-Iodooctane 
• 3386-35-4 1-octyl p-toluenesulfonate 
• 30008-10-7 sodium 4-hydroxybenzen-1-olate 

Downstream Products

• 77892-62-7 2-Nitro-1,4-bis-octyloxy-benzene 
• 1263321-01-2 C₂₄H₃₈F₃NO₃ 
• 1263321-03-4 C₂₄H₃₇F₃N₂O₅ 
• 1263321-06-7 C₂₄H₃₉F₃N₂O₃ 
• 1263321-09-0 C₅₃H₈₅F₃N₂O₅ 
• 1263321-12-5 C₅₁H₈₆N₂O₄ 
• 123440-34-6 2,5-bis(octyloxy)-1,4-benzenecarboxaldehyde 
• 431898-09-8 2,5-bis(octyloxy)-4-bromo-benzaldehyde 
• 194204-72-3 1-bromo-4-iodo-2,5-bis(octyloxy)benzene 
• 935510-50-2 C₅₃H₈₄N₄O₇ 
• 935510-49-9 C₂₂H₃₆O₂NH₂NH₂ 
• 194204-71-2 2-bromo-1,4-bis(octyloxy)benzene 
• 156028-40-9 1,4-dibromo-2,5-dioctyloxyphenylene 

Relevant articles and documents

Patterned monolayers of neutral and charged functionalized manganese arene complexes on a highly ordered pyrolytic graphite surface

Complex patterns: The arene manganese tricarbonyl complexes [Mn( 5-2,5-didodecoxy-1,4-semiquinone)(CO)3] and [Mn( 6-1,4-dioctyloxybenzene)(CO)3] BF4 form patterned monolayers on the surface of highly ordered pyrolytic graphite (HOPG), as a result of hydro

Bipyridyl ligand and preparation method thereof, ruthenium supramolecular self-assembly body containing bipyridyl ligand and preparation method and application of ruthenium supramolecular self-assembly

The invention provides a novel bipyridyl bidentate ligand and a preparation method thereof. The structural formula of the novel bipyridyl bidentate ligand is shown in the specification. The inventionfurther provides a ruthenium supramolecular self-assembly body of the ligand and a preparation method of the ruthenium supramolecular self-assembly body. The preparation method comprises the followingsteps: putting a prepared ruthenium receptor and a bipyridyl ligand into a container, adding a mixed solvent of methanol and dichloromethane in equal proportion, stirring for a period of time at roomtemperature, spin-drying the solution to a certain volume after the reaction is finished, slowly adding diethyl ether, and separating out solid powder, namely the ruthenium supramolecular self-assembly body containing the bipyridyl ligand. The self-assembly body is a novel ruthenium-containing self-assembly compound, and has a good inhibition effect on cancer tumor cell lines A549 and HepG-2.

Functional phenylethynylene side arm poly(arylene ethynylene) conjugated polymers: Optical and electrochemical behavior for enrichment of electronic applications

The poly(arylene ethynylene) (PAE) conjugated polymers (CPs) with a donor-acceptor (D-A) side arm have been designed and synthesized using Sonogashira cross coupling in the presence of cyano methylene, or cyano thiophene gave diethynyl (A) and alkoxy and alkyl substituted diiodo aryl monomers (D). An interesting electronic response in optical measurements such as UV-visible (UV-vis) and fluorescence (FL) spectra was observed in tetrahydrofuran solvent. From the FL spectra, it was observed that the CP solutions possess an interesting long bathochromic shift when compared with the UV-vis spectra, because of the electron withdrawing, electron releasing and conjugation effects. The electrochemical and thin film UV-vis spectral measurements provided highest occupied molecular orbital-lowest unoccupied molecular orbital (HOMO-LUMO) electronic energy levels and their corresponding semiconducting electronic energy gaps (Eg) of the PAE CPs. Among the side arm CPs, polymers P1 and P5 have low Eg of 2.14 eV and 2.17 eV. The new PAE CPs are reliable for use in electronic and photonics applications.