935693-46-2Relevant academic research and scientific papers
Stereoselective double alkylation of the acetoacetate ester α-carbon on a D-glucose-derived template: Application to the synthesis of enantiopure cycloalkenones bearing an asymmetric quaternary carbon
Kozawa, Ikuko,Akashi, Yoko,Takiguchi, Kumiko,Sasaki, Daisuke,Sawamoto, Daisuke,Takao, Ken-Ichi,Tadano, Kin-Ichi
, p. 399 - 402 (2007/12/27)
The previously developed D-glucose derivative, i.e., methyl 6-deoxy-2,3-di-O-(tert-butyldimethylsilyl)-α-D-glucopyranoside, served as a significant stereocontrolling element for the diastereoselective alkylation of the α-carbon in its acetoacetate at C-4
