935733-35-0Relevant academic research and scientific papers
Dual Rh(II)/Pd(0) Relay Catalysis for One-Pot Synthesis of α-Quaternary Allylated Indolin-2-ones and Benzofuran-2-ones
Lee, Yu Lim,Lee, Kyu Ree,Xuan, Zi,Lee, Sang-gi
, p. 537 - 541 (2021/01/12)
Cooperative Rh(II) and Pd(0) dual relay catalysis has been developed, which allowed one-pot synthesis of α-quaternary allylated indolin-2-ones and benzofuran-2-ones. The catalytic reaction proceeded through the sequential Rh(II)-catalyzed intramolecular aromatic C(sp2)-H bond functionalization of α-diazo carbonyl compounds, followed by Pd(0)-catalyzed allylic alkylation with allylic carbonates to afford the products in high yields (up to 97%).
Catalytic oxidation/C-H functionalization of N-arylpropiolamides by means of gold carbenoids: Concise route to 3-acyloxindoles
Qian, Deyun,Zhang, Junliang
, p. 7082 - 7084 (2012/08/07)
An efficient catalytic C-H functionalization by means of gold carbenoids for the one-step synthesis of 3-acyloxindole derivatives has been developed. The reaction proceeds efficiently with extremely good substrate scope and significant opportunities for s
