935733-46-3

Upstream product

• 2100-17-6 4-pentenal 
• 101711-78-8 (3R)-3-propionyl-4-benzyloxazolidin-2-one 
• 111957-98-3 Pent-4-en-2-ol 

Downstream Products

• 935733-56-5 (3R,3aR,7S,8aR,Z)-6-[2-(tert-butyldiphenylsilyloxy)ethyl]-3,7-dimethyl-3,3a,4,7,8,8a-hexahydro-2H-cyclohepta[b]furan-2-one 
• 935733-55-4 (3aR,7S,8aR,Z)-6-[2-(tert-butyldiphenylsilyloxy)ethyl]-7-methyl-3,3a,4,7,8,8a-hexahydro-2H-cyclohepta[b]furan-2-one 
• 935733-59-8 6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-7-methyl-3,3a,4,7,8,8a-hexahydro-2H-cyclohepta[b]furan-2-ol 

Relevant academic research and scientific papers

Total Synthesis of Macrocyclic Dysoxylactam A

The total synthesis of dysoxylactam A, a novel 17-membered macrolactam with potent multi-drug-resistant reversing activities, has been achieved, starting from 4-pentene-1-al in a longest linear sequence of 17 steps and 9.5percent overall yield. The key transformations consist of iterative aldol and ring-closing metathesis reactions for the construction of the stereochemically enriched polypropionate scaffold and the macrocycle, respectively.

Total synthesis of (+)-sundiversifolide

(Chemical Equation Presented) The first, enantiocontrolled total synthesis of (+)-sundiversifolide has been accomplished using the sequential ring-closing metathesis, [3,3]-sigmatropic rearrangement, and iodolactonization for the key assembly of the cis-f