93578-99-5Relevant academic research and scientific papers
Compounds useful as phosphotyrosine mimics
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, (2008/06/13)
Disclosed are compositions containing compounds of the formula (I) below wherein A,B,C,G,Q and R are defined herein. The compounds are useful as phosphotyrosine mimics that, when incorporated into an appropriate molecular structure, inhibit the binding of
Mono- and Bi-metallic Catalysed Formate-Halide Carbonylation Reactions
Buchan, Caroline,Hamel, Nathalie,Woell, James B.,Alper, Howard
, p. 167 - 168 (2007/10/02)
Benzylic, aryl, and alkyl halides react with formate esters and carbon monoxide, in the presence of the dimer of chloro(hexa-1,5-diene)rhodium(I), 2, to give carboxylic esters: bimetallic catalysis 2> is particularly beneficial when an aromatic halide is used as the substrate.
RHODIUM(I) CATALYZED CARBONYLATION REACTIONS OF HALIDES AND ETHERS
Buchan, Caroline,Hamel, Nathalie,Woell, James B.,Alper, Howard
, p. 5743 - 5746 (2007/10/02)
Benzylic bromides and methyl ioide react with ethers, carbon monoxide, potassium iodide, and the dimer of chloro(1,5-hexadiene)rhodium(I) to give esters in good yields.
SYNTHESIS OF ESTERS BY RHODIUM(I) CATALYZED BORATE ESTER-BENZYLIC BROMIDE CARBONYLATION REACTIONS
Woell, James B.,Alper, Howard
, p. 3791 - 3794 (2007/10/02)
Benzylic halides react with trialkylborates and carbon monoxide, in the presence of 1,5-hexadienerhodium chloride dimer, to give esters in excellent yields.The reaction is applicable to the synthesis of primary, secondary and even tertiary esters.
