93601-17-3Relevant academic research and scientific papers
SYNTHESIS OF NOVEL BRANCHED-CHAIN AMINO SUGARS: METHYL L-SIBIROSAMINIDE AND N-ACYLKANSOSAMINE
Yoshimura, Juji,Aqeel, Amjad,Sato, Ken-Ichi,Singh, Rhiddi Bir,Hashimoto, Hironobu
, p. 253 - 262 (2007/10/02)
Methyl L-sibirosaminide and N-acylkansosamine were synthesized via the same intermediate, methyl 4-amino-4,6-dideoxy-2,3-O-isopropylidene-3-C-methyl-α-L-mannopyranoside (7), from L-rhamnose in 7 and 10 steps, respectively.Conversion of 7 into the title co
α-Amino Acids as Chiral Educts for Asymmetric Products. Chirospecific Syntheses of Methyl L-Sibirosaminide and Its C-3 Epimer from L-Allothreonine
Maurer, Peter J.,Knudsen, Christopher G.,Palkowitz, Alan D.,Papoport, Henry
, p. 325 - 332 (2007/10/02)
Efficient syntheses of methyl L-sibirosaminide and its C-3 epimer are described using L-allothreonine as the chiral educt.Amino acylations of organometallics with the lithium salt of N-(phenylsulfonyl)-L-allothreonine constitute the key carbon-carbon bond
