93474-76-1

Upstream product

• 121359-97-5 methyl 6-deoxy-2,3-O-isopropylidene-3-C-methyl-4-O-(methylsulfonyl)-α-L-mannopyranoside 
• 121359-93-1 methyl 6-deoxy-2,3-O-isopropylidene-3-C-methyl-α-L-mannopyranoside 
• 121359-98-6 methyl 6-deoxy-3-C-methyl-4-O-(methylsulfonyl)-α-L-mannopyranoside 
• 104874-61-5 methyl 6-deoxy-3-C-methyl-α-L-mannopyranoside 
• 67-56-1 methanol 
• 121359-99-7 methyl 3,4-anhydro-6-deoxy-3-C-methyl-α-L-talopyranoside 
• 83465-17-2 sodium N-methyl-N-phenylsulfonylamide 

Downstream Products

• 93601-17-3 methyl 3-methyl-4-methylamino-α-L-4,6-dideoxy-mannopyranoside 

Relevant academic research and scientific papers

Synthesis of branched-chain sugars: a stereoselective route to sibirosamine, kansosamine, and vinelose from a common precursor.

Methyl 4,6-dideoxy-3-C-methyl-4-(N-methyl-N-phenylsulfonylamino)-alpha-L- mannopyranoside and methyl 4-amino-4,6-dideoxy-3-C-methyl-alpha-L-mannopyranoside, derivatives of the branched-chain amino sugars sibirosamine and kansosamine, respectively, were sy

α-Amino Acids as Chiral Educts for Asymmetric Products. Chirospecific Syntheses of Methyl L-Sibirosaminide and Its C-3 Epimer from L-Allothreonine

Efficient syntheses of methyl L-sibirosaminide and its C-3 epimer are described using L-allothreonine as the chiral educt.Amino acylations of organometallics with the lithium salt of N-(phenylsulfonyl)-L-allothreonine constitute the key carbon-carbon bond