936482-29-0

Basic information

• Product Name: N-((Z)-1,3-dimethylbuta-1,3-dienyl)benzamide
• Synonyms: N-((Z)-1,3-dimethylbuta-1,3-dienyl)benzamide
• CAS NO: 936482-29-0
• Molecular Weight: 201.268
• Mol File: 936482-29-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-((Z)-1,3-dimethylbuta-1,3-dienyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-((Z)-1,3-dimethylbuta-1,3-dienyl)benzamide(936482-29-0)
• EPA Substance Registry System: N-((Z)-1,3-dimethylbuta-1,3-dienyl)benzamide(936482-29-0)

Safety Data

• Hazardous Substances Data: 936482-29-0(Hazardous Substances Data)

Upstream product

• 123-54-6 acetylacetone 
• 55-21-0 benzamide 
• 23112-27-8 N-((Z)-1-methyl-3-oxobut-1-enyl)benzamide 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 936482-38-1 3-benzylamino-3,5-dimethylcyclohexa-1,4-dienecarboxylic acid methyl ester 
• 24374-32-1 exo-N-bicyclo[2.2.1]heptan-2-yl-benzamide 

Relevant articles and documents

Radical transfer hydroamination with aminated cyclohexadienes using polarity reversal catalysis: Scope and limitations

The synthesis of various new 1-aminated-2,5-cyclohexadienes is described. These reagents can be used in radical transfer hydroaminations of unactivated and electron-rich double bonds. With thiols as polarity reversal catalysts good yields are obtained. The radical hydroamination occurs with good to excellent anti-Markovnikov selectivity. Many functional groups such as alcohols, silyl ethers, phosphonates, arylbromides, imides, amides, and also acidic protons are tolerated under the reaction conditions. DFT calculations provide insights into the aromatization of silyl, alkyl, and aminyl substituted cyclohexadienyl radicals to generate the corresponding C-, Si-, and N-centered radicals.