936731-49-6Relevant academic research and scientific papers
On the structure of the Phytophthora α1 mating hormone: synthesis and comparison of four candidate stereoisomers
Bajpai, Reena,Yang, Fanglong,Curran, Dennis P.
, p. 7965 - 7968 (2007)
Two two-compound mixtures of candidate structures for the Phytophthora α1 mating hormone have been synthesized. The mixtures were designed to have differing configurations at C3, but proved to be identical. This suggests that epimerization occurred at C3,
Asymmetric Total Syntheses of (?)-α-Lycorane, (?)-Zephyranthine, and Formal Synthesis of (+)-Clivonine
Chen, Yong-Jian,Cai, Sen-Lin,Wang, Chuan-Chuan,Cheng, Jin-Duo,Kramer, S?ren,Sun, Xing-Wen
supporting information, p. 1309 - 1313 (2017/06/23)
An asymmetric route to (?)-α-lycorane and (?)-zephyranthine, and a formal total synthesis of (+)-clivonine were achieved. A pivotal intermediate, which serves as a potent precursor for the divergent syntheses of these natural products, was accessed by a diastereoselective Pd-catalyzed cinnamylation of an N-tert-butanesulfinyl imine.
Asymmetric synthesis of (E)-dehydroapratoxin A
Ma, Jing-Yi,Huang, Wei,Wei, Bang-Guo
, p. 4598 - 4601 (2011/09/30)
An asymmetric approach to key intermediate 17 starting from lactone 7 is described, in which Evan's alkylation and CBS-catalyzed reduction are used for construction of the chiral centers, respectively. Thus, the synthesis of (E)-dehydroapratoxin A 6 could
CERTAIN CHEMICAL ENTITIES, COMPOSITIONS, AND METHODS
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Page/Page column 65, (2010/11/27)
Compounds useful for treating cellular proliferative diseases and disorders by modulating the activity of one or more mitotic kinesins are disclosed.
