936915-83-2

Upstream product

• 936915-84-3 (2R)-1,2-(cyclohexylidenedioxy)hept-6-en-3-one 
• 943154-81-2 (2R,3S/R)-1,2-(cyclohexylidenedioxy)hept-6-en-3-ol 
• 78008-36-3 (R)-2,3-cyclohexylideneglyceraldehyde 
• 113730-85-1 (S)-1-((R)-1,4-dioxaspiro[4.5]decan-2-yl)pent-4-en-1-ol 
• 98-88-4 benzoyl chloride 

Downstream Products

• 254891-76-4 (2R,5S)-cis-5-ethynyl-2-[(p-toluenesulfonyloxy)methyl]tetrahydrofuran 
• 254891-75-3 (2R,5S)-cis-5-ethynyl-2-(hydroxymethyl)tetrahydrofuran 
• 936915-92-3 benzoic acid 1-(1,4-dioxa-spiro[4.5]dec-2-yl)-4-hydroxy-5-(toluene-4-sulfonyloxy)-pentyl ester 
• 936915-93-4 tert-butyl-[5-(1,4-dioxa-spiro[4.5]dec-2-yl)-tetrahydro-furan-2-ylmethoxy]-diphenyl-silane 
• 936915-94-5 1-[5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-ethane-1,2-diol 
• 936915-96-7 tert-butyl-(5-ethynyl-tetrahydro-furan-2-ylmethoxy)-diphenyl-silane 
• 936915-95-6 5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-carbaldehyde 
• 936915-91-2 benzoic acid 1-(1,4-dioxa-spiro[4.5]dec-2-yl)-4,5-dihydroxy-pentyl ester 

Relevant academic research and scientific papers

Stereoselective approach to (2R,3S)- and (2R,3R)-1,2-(cyclohexylidenedioxy) hept-6-en-3-ol by microbial reduction

Among twelve incubated whole-cell yeast strains, two were found to selectively reduce (R)-1,2-(cyclohexylidenedioxy)hept-6-en-3-one, which was derived from d-mannitol. Pichia minuta JCM 3622 and Rhodotorula mucilaginosa NBRC 0889 afforded (2R,3S)-form (97

(R)-2,3-Cyclohexylideneglyceraldehyde: a novel template for simple entry into both cis- and trans-2,5-disubstituted tetrahydrofurans

Sharpless asymmetric dihydroxylation at the terminal olefin of benzoates 3a and 3b, using both AD-mix α and AD-mix β afforded only one diastereomer of diols 5a and 5b, respectively. Diols 5a and 5b were easily transformed into cis- and trans-2,5-disubstit