936946-32-6

Basic information

• Product Name: (R)-4-benzyl-3-((S,E)-2,4-dimethylhex-4-enoyl)oxazolidin-2-one
• Synonyms: (R)-4-benzyl-3-((S,E)-2,4-dimethylhex-4-enoyl)oxazolidin-2-one
• CAS NO: 936946-32-6
• Molecular Weight: 301.386
• Mol File: 936946-32-6.mol

Chemical Properties

• CAS DataBase Reference: (R)-4-benzyl-3-((S,E)-2,4-dimethylhex-4-enoyl)oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-benzyl-3-((S,E)-2,4-dimethylhex-4-enoyl)oxazolidin-2-one(936946-32-6)
• EPA Substance Registry System: (R)-4-benzyl-3-((S,E)-2,4-dimethylhex-4-enoyl)oxazolidin-2-one(936946-32-6)

Safety Data

• Hazardous Substances Data: 936946-32-6(Hazardous Substances Data)

Upstream product

• 57253-30-2 tiglyl bromide 
• 101711-78-8 (3R)-3-propionyl-4-benzyloxazolidin-2-one 
• 66702-98-5 (E)-1-iodo-2-methyl-but-2-ene 
• 40217-17-2 (R)-4-(phenylmethyl)-2-oxazolidinone 
• 5837-78-5 Ethyl tiglate 
• 497-02-9 (E)-2-methyl-2-buten-1-ol 
• 80-59-1 Tiglic acid 

Downstream Products

• 936946-38-2 (2'S,3'R,4'S,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-hydroxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone 
• 936946-36-0 (2'S,3'R,4'R,5'S,6'S,8E,4S)-3-[(5-[tert-butyldimethylsilyloxy]-3-triethylsilyloxyl-2,4,6,8-tetramethyl-1-oxo-dec-8-enyl)-4-(phenylmethyl)]-2-oxazolidinone 
• 936946-39-3 C₂₄H₃₅NO₅ 
• 936946-34-8 C₃₀H₄₇NO₅Si 

Relevant articles and documents

Accessing the structural diversity of pyridone alkaloids: Concise total synthesis of rac-citridone A

A unique route to the structural diversity of pyridone alkaloids is described based on the concept of a common synthetic strategy. Three different core structure analogues corresponding to akanthomycin, septoriamycin A, and citridone A have been prepared by using a highly selective and novel carbocyclization reaction.

Synthesis of the C10-C32 core structure of spirangien A

(Chemical Equation Presented) The synthesis of the C10-C32 core structure of spirangien A is reported. The pivotal aldol coupling between both key intermediates provides a synthetic challenge in the synthesis of this complex natural product.

Synthesis of the C23-C32 fragment of spirangien

The synthesis of the C23-C32 fragment of spirangien A is reported using Evans' alkylation, Evans-Metternich aldol reaction and a substrate controlled stereoselective reduction.