93696-65-2

Upstream product

• 6286-30-2 2,3-dibromo-3-phenylpropanoic acid 
• 36914-22-4 2,3-Dibromo-3-phenyl-propionaldehyde oxime 
• 102-92-1 cinnamoyl chloride 

Downstream Products

• 94880-23-6 2,3-Dibrom-3-phenyl-propionsaeure-diphenylamid 
• 92846-21-4 2,3-Dibrom-3-phenyl-propionsaeure-dimethylamid 
• 90841-78-4 2,3-dibromo-3-phenyl-propionic acid methylamide 
• 89696-47-9 2,3-Dibrom-3-phenyl-propionsaeure- 
• 93500-97-1 p-cresyl α,β-dibromohydrocinnamate 
• 112122-61-9 1-[4-(Bromo-phenyl-methyl)-5-oxo-[1,3]dithiolan-2-ylidene]-pyrrolidinium; bromide 
• 112122-60-8 1-[4-(Bromo-phenyl-methyl)-5-oxo-[1,3]dithiolan-2-ylidene]-piperidinium; bromide 
• 112122-62-0 4-[4-(Bromo-phenyl-methyl)-5-oxo-[1,3]dithiolan-2-ylidene]-morpholin-4-ium; bromide 
• 93696-68-5 2,3-Dibromo-N-(4-chloro-phenyl)-3-phenyl-propionamide 
• 93500-91-5 α,β-dibromohydrocinnamanilide 
• 93501-02-1 p-thiocresyl α,β-dibromohydrocinnamate 
• 40326-95-2 phenyl α,β-dibromohydrocinnamate 
• 881994-36-1 4-formyl-2-methoxyphenyl 1,2-dibromo-2-phenylpropionate 
• 97598-41-9 cis-α-Brom-zimtsaeure-(N-methyl-anilid) 

Relevant academic research and scientific papers

Crystal structure, characterization, Hirshfeld surface analysis and DFT studies of two [propane 3-bromo-1-(triphenyl phosphonium)] cations containing bromide (I) and tribromide (II) anions: The anion (II) as a new brominating agent for unsaturated compounds

In this study, propane 3-bromo-1- (triphenyl phosphonium) bromide, I, and propane 3-bromo-1- (triphenyl phosphonium) tribromide, II, (II as a new brominating agent) were synthesized and characterized by 1H NMR, 13C NMR, 31P NMR, FT-IR, spectroscopy, Thermogravimetric Analysis, Differential thermal analysis, Differential scanning calorimetry and single crystal X-ray analysis. Density functional theory calculations (energy, structural optimization and frequencies, Natural Bond Orbital, absorption energy and binding energy) were performed by using B3LYP/6-311 G++ (d, p) level of theory. Hirshfeld surface analysis and fingerprint plots were utilized to investigate the role of bromide and tribromide anions on the crystal packing structures of title compounds. The results revealed that the change of accompanying anionic moiety can affect the directional interactions of C-H?Br hydrogen bonds between anionic and cationic units in which the H?Br with a proportion of 53.8% and 40.9% have the major contribution in the stabilization of crystal structures of I and II, respectively. Furthermore, the thermal stability of new brominating agent II with tribromide anion was compared with compound I with bromide anion. Nontoxicity, short reaction time, thermal stability, simple working up and high yield are some of the advantages of these salts.

New esters of vanillin and vanillal with some alkane- and arenecarboxylic acids

Previously unknown esters were synthesized by the reaction of vanillin and vanillal with carboxylic acid chlorides. Pleiades Publishing, Inc., 2006.

Esters derived from vanillin and vanillal and aromatic and functionalized aliphatic carboxylic acids

Reactions of vanillin and vanillal with aromatic and functionally substituted aliphatic carboxylic acid chlorides in the presence of pyridine afforded the corresponding previously unknown esters.

Photochemical debromination of vic-dibromides

Photochemical debromination of dibromohydro cinnamamides gave the carbon-carbon double bond compounds.

Synthesis of 3-Arylcoumarins, Thiacoumarins and Carbostyrils

3-Arylcarbostyrils (2a-f), coumarins (2g-j) and thiacoumarin (2k) have been prepared by a generalised method from α,β-dibromohydrocinnamoyl derivatives (1a-k).The intermediate dihydrocoumarins and dihydrocarbostyrils (3, Y = O, NH) have been prepared which on acid treatment furnish 2.However, treatment of 3 with a base affords the 4-arylcoumarins and carbostyrils (4).