93746-68-0Relevant academic research and scientific papers
SYNTHESE UND REAKTIONEN DER 2,4,6-TRI-TERT-BUTYLPHENYLDIHALOGENMETHYLENPHOSPHANE1
Appel, Rolf,Casser, Carl,Immenkeppel, Michael
, p. 3551 - 3554 (2007/10/02)
The synthesis of dihalogenated phosphaalkanes 2a,b is reported.After metallation with n-BuLi they could be substituted by halogenated compounds.
REAKTIONEN DES 2,4,6-TRI-TERT-BUTYLPHENYLPHOSPHANS
Appel, Rolf,Casser, Carl
, p. 4109 - 4112 (2007/10/02)
The reaction of phosphaalkene 1 with ozone, sulfur and selenium yields the phosphoranes 2, 3 and 4.The methylene halogene substituted phosphaalkene 5 is formed with bromine.The bipyramidal iron carbonyl complexes 8 and 9 are obtained by reaction of 1 and 7 with Fe2(CO)9.
