93777-44-7

Usage

InChI:InChI=1/C12H20O2/c1-11(2)7-4-8-12(3)9(11)5-6-10(13)14-12/h9H,4-8H2,1-3H3

Upstream product

• 40518-76-1 5,9-dimethyldeca-4,8-dienoic acid 
• 96557-57-2 (+/-)-3-(2c-hydroxy-2t,6,6-trimethyl-cyclohex-r-yl)-propionic acid 
• 5579-63-5 geranylacetic acid 
• 52567-87-0 (1R*,2S*)-2-(3-Hydroxypropyl)-1,3,3-trimethyl-1-cyclohexanol 
• 77837-97-9 2-geranylthiophene-5-carboxylic acid 
• 70006-15-4 2-geranylthiophene 
• 6138-90-5 trans-geranyl bromide 
• 154084-90-9 (+/-)-3-(2-Iodoethyl)-2,4,4-trimethyl-1-cyclohexene 
• 472-63-9 2-(2,6,6-trimethyl-cyclohex-2-enyl)-ethanol 
• 178616-48-3 (+/-)-Ethyl 2-<2-(2,6,6-trimethyl-2-cyclohexen-1-yl)ethyl>-3-oxobutanoate 

Downstream Products

• 96557-57-2 (+/-)-3-(2c-hydroxy-2t,6,6-trimethyl-cyclohex-r-yl)-propionic acid 
• 52567-87-0 (1R*,2S*)-2-(3-Hydroxypropyl)-1,3,3-trimethyl-1-cyclohexanol 

Relevant academic research and scientific papers

CATIONIC CYCLIZATION OF LINALYL- AND GERANYL/NERYLACETIC ACID. A FACILE ENTRY TO THE BREXANE SYSTEM

Linalyl- and geranyl/nerylacetic acid on acid-catalysis from bicyclic lactones which with PPA afford tetrahydroindanones 6, 7, and the 2-brexanone 12 respectively.

Calcium(II)- And Triflimide-Catalyzed Intramolecular Hydroacyloxylation of Unactivated Alkenes in Hexafluoroisopropanol

We report an efficient intramolecular hydroacyloxylation of unactivated alkenes, offering a streamlined access to relevant γ-lactones, which features the utilization of either a calcium(II) salt or triflimide as a catalyst in hexafluoroisopropanol. This method could be applied to the synthesis of natural products and the late-stage functionalization of natural and bioactive molecules. Additionally, DFT computations were used to elucidate the twist of reactivity observed between the hydroamidation and hydroacyloxylation of unactivated alkenes regarding the formation of 5- and 6-membered rings.

Synthesis of mono- and sesquiterpenoids, XXV: Synthesis of (6R*,7R*)-7-hydroxy-6,11-cyclofarnes-3(15)-en-2-one, the racemate of the antibacterial sesquiterpene from premna oligotricha, and its (6R*,7R*) isomer

The structure of the antibacterial sesquiterpene from Premna oligotricha was shown to be not 1 but 2 (relative stereochemistry) by the unambiguous synthesis of both (±)-1 and (±)-2. VCH Verlagsgesellschaft mbH, 1996.