93796-39-5

Basic information

• Product Name: 1,4-Dioxaspiro[4.5]decan-2-one, 3-(triphenylphosphoranylidene)-
• CAS NO: 93796-39-5
• Molecular Formula: C26H25O3P
• Molecular Weight: 416.456
• Mol File: 93796-39-5.mol

Chemical Properties

• CAS DataBase Reference: 1,4-Dioxaspiro[4.5]decan-2-one, 3-(triphenylphosphoranylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Dioxaspiro[4.5]decan-2-one, 3-(triphenylphosphoranylidene)-(93796-39-5)
• EPA Substance Registry System: 1,4-Dioxaspiro[4.5]decan-2-one, 3-(triphenylphosphoranylidene)-(93796-39-5)

Safety Data

• Hazardous Substances Data: 93796-39-5(Hazardous Substances Data)

Upstream product

• 94034-49-8 5'-bromocyclohexanespiro-2'-(1',3'-dioxolan)-4'-one 
• 4423-79-4 cyclohexanespiro-2'-(1',3'-dioxolan)-4'-one 
• 94034-50-1 5'-oxocyclohexanespiro-2'-(1',3'-dioxolan)-4'-yltriphenylphosphonium bromide 
• 94034-50-1 ((R)-3-Oxo-1,4-dioxa-spiro[4.5]dec-2-yl)-triphenyl-phosphonium; bromide 

Downstream Products

• 94034-54-5 (Z)-5'-(4-benzyloxybenzylidene)cyclohexanespiro-2'-(1',3'-dioxolan)-4'-one 
• 110115-72-5 4-Hydroxy-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 110115-71-4 4-Hydroxy-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 94493-00-2 2,6-Diacetoxy-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-4-trimethylsilanyloxy-cyclohex-3-enecarboxylic acid methyl ester 
• 94492-99-6 6-Acetoxy-2-methoxy-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-4-trimethylsilanyloxy-cyclohex-3-enecarboxylic acid methyl ester 
• 94493-01-3 6-Acetoxy-4-oxo-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohex-2-enecarboxylic acid methyl ester 
• 110115-73-6 4-Formyloxy-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 94493-06-8 6-Methoxy-4-oxo-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohex-2-enecarboxylic acid methyl ester 
• 110065-30-0 4-Oxo-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 94034-68-1 5'-benzylcyclohexanespiro-2'-(1',3'-dioxolan)-4'-one 
• 94034-67-0 5'-cyclohexylmethylcyclohexanespiro-2'-(1',3'-dioxolan)-4'-one 
• 108-94-1 cyclohexanone 
• 590-67-0 1-Methylcyclohexanol 
• 4423-79-4 cyclohexanespiro-2'-(1',3'-dioxolan)-4'-one 

Relevant articles and documents

SYNTHESIS OF DISODIUM PREPHENATE

An efficient synthesis of disodium prephenate is described which illustrates the use of 5-ylidene-1,3-dioxalan-4-ones for the synthesis of acid labile α-keto acids.

Dioxolanones as Synthetic Intermediates. Part 1. Synthesis of α-Keto Acids, α-Keto Aldehydes, and α-Ketols

2,2-Pentamethylene-1,3-dioxolan-4-one (10) has been elaborated to provide 5'-ylidene derivatives using a Wittig approach.This apparently novel class of compounds is subject to nucleophilic attack at the 4-position because of strain inherent in the 5-membered ring.Thus alkaline hydrolysis leads to the formation of α-keto acids; hydride reduction of dioxolanones incorporating conjugated aryl substituents using di-isobutylaluminium hydride leads to α-keto-aldehydes; the reaction of dioxolanone (15) with methylmagnesium iodide gave the α-ketol (40).