94493-00-2

Upstream product

• 110065-32-2 1-acetoxy-3-<(trimethylsilyl)oxy>buta-1,3-diene 
• 110082-50-3 (E)-3-Acetoxy-2-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-acrylic acid methyl ester 
• 110065-31-1 (Z)-3-Acetoxy-2-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-acrylic acid methyl ester 
• 87682-18-6 (E)-3-Acetoxy-2-formyl-acrylic acid methyl ester 
• 94034-50-1 5'-oxocyclohexanespiro-2'-(1',3'-dioxolan)-4'-yltriphenylphosphonium bromide 
• 93796-39-5 5'-triphenylphosphoranylidenecyclohexanespiro-2'-(1',3'-dioxolan)-4'-one 
• 64516-52-5 2-(methoxycarbonyl)malonaldehyde 
• 51731-15-8 trans-3-oxo-1-butenyl acetate 

Downstream Products

• 110115-71-4 4-Hydroxy-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 110115-72-5 4-Hydroxy-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 110115-73-6 4-Formyloxy-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 94493-01-3 6-Acetoxy-4-oxo-1-[3-oxo-1,4-dioxa-spiro[4.5]dec-(2Z)-ylidenemethyl]-cyclohex-2-enecarboxylic acid methyl ester 

Relevant academic research and scientific papers

SYNTHESIS OF DISODIUM PREPHENATE

An efficient synthesis of disodium prephenate is described which illustrates the use of 5-ylidene-1,3-dioxalan-4-ones for the synthesis of acid labile α-keto acids.

Synthesis of Disodium Prephenate

An efficient synthesis of disodium prephenate has been achieved utilising a 5-ylidene-1,3-dioxolan-4-one intermediate as a protected α-keto acid.