938-04-5

Upstream product

• 64-18-6 formic acid 
• 585-32-0 2-phenyl-2-propylamine 
• 826-54-0 2-methyl-2-phenyl-propanamide 
• 50-00-0 formaldehyd 
• 5419-55-6 Triisopropyl borate 
• 2273-40-7 2-dimethylamino-2-methylpropionitrile 

Downstream Products

• 826-55-1 2-methyl-2-phenylpropionic acid 
• 860701-93-5 dimethyl-(1-methyl-1-phenyl-ethyl)-amine oxide 

Relevant academic research and scientific papers

Dramatic enhancement of the stability of rare-earth metal complexes with α-methyl substituted N,N-dimethylbenzylamine ligands

Stepwise substitution of benzylic CH2 protons in ortho-metallated N,N-dimethylbenzylamine (dmba) ligands leads to chiral ortho-metallated N,N,α-trimethylbenzylamine (tmba) and cumyl-N,N-dimethylamine (cuda) ligands. These larger ligands with le

Ortho-metalated, chelate-stabilized benzylamines of the rare-earth metals (RE) Ar3RE

The present invention describes homoleptic, ortho-metalated, chelate-stabilized benzylamine complexes of the rare-earth metals. The rare-earth metals are selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. In the complexes acc

Deprotonation from an N-methyl group in 2-[1-(dimethylamino)-1-methylethyl]phenylborane derivatives

Reaction of 2-[1-(dimethylamino)-1-methylethyl]phenyllithium (Ar*Li) with a trialkyl borate, B(OR)3, in the 3:1 ratio gave 1-Ar*-3,4,4-trimethyl-1,2,3,4-tetrahydro-3,1-benzazaborin as a major product together with the corresponding protonated compound and the boronic acid. The structure of the hetelocyclic compound was determined by X-ray analysis and NMR spectroscopy. This compound is formed via the deprotonation from one of the N-Me groups in Ar*2B(OR) by the remaining Ar*Li followed by the facile intramolecular cyclization between the boron and carbon atoms.