938080-25-2Relevant academic research and scientific papers
Nickel-Catalyzed Regioselective Alkenylarylation of γ,δ-Alkenyl Ketones via Carbonyl Coordination
Aryal, Vivek,Dhungana, Roshan K.,Giri, Ramesh,Lakomy, Margaret G.,Niroula, Doleshwar,Sapkota, Rishi R.
supporting information, p. 19092 - 19096 (2021/08/09)
We disclose a nickel-catalyzed reaction, which enabled us to difunctionalize unactivated γ,δ-alkenes in ketones with alkenyl triflates and arylboronic esters. The reaction was made feasible by the use of 5-chloro-8-hydroxyquinoline as a ligand along with
Ruthenium-Catalyzed Monoalkenylation of Aromatic Ketones by Cleavage of Carbon-Heteroatom Bonds with Unconventional Chemoselectivity
Kondo, Hikaru,Akiba, Nana,Kochi, Takuya,Kakiuchi, Fumitoshi
supporting information, p. 9293 - 9297 (2015/08/06)
Ruthenium-catalyzed selective monoalkenylation of ortho C-O or C-N bonds of aromatic ketones was achieved. The reaction allowed the direct comparison of the relative reactivities of the cleavage of different carbon-heteroatom bonds, thus suggesting an unc
Nickel-catalysed carboxylation of organoboronates
Makida, Yusuke,Marelli, Enrico,Slawin, Alexandra M. Z.,Nolan, Steven P.
supporting information, p. 8010 - 8013 (2014/07/08)
A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO 2 with a broad range of substrates and exhibits good functional group compatibility. the Partner Organisations 2014.
Copper(I)-catalyzed carboxylation of aryl- and alkenylboronic esters
Takaya, Jun,Tadami, Satoshi,Ukai, Kazutoshi,Iwasawa, Nobuharu
supporting information; experimental part, p. 2697 - 2700 (2009/05/26)
(Chemical Equation Presented) The copper(I)-catalyzed carboxylation reaction of aryl- and alkenylboronic esters proceeded smoothly under CO 2 to give the corresponding carboxylic acid in good yield. This reaction showed wide generality with higher functional group tolerance compared to the corresponding Rh(I)-catalyzed reaction.
