93826-92-7Relevant academic research and scientific papers
COMPLETELY STEREOSPECIFIC 1,2-MIGRATION OF ALKYL GROUPS IN Et2AlCl PROMOTED PINACOL-TYPE REARRANGEMENT
Tsuchihashi, Gen-ichi,Tomooka, Katsuhiko,Suzuki, Keisuke
, p. 4253 - 4256 (1984)
Completely stereospecific 1,2-migration of alkyl groups was achieved in Et2AlCl-promoted pinacol-type rearrangement of chiral β-mesyloxy alcohols to give optically pure α-alkyl ketones including both enantiomers of 4-methyl-3-hexanone, an alarm pheromone of ant.
