COMPLETELY STEREOSPECIFIC 1,2-MIGRATION OF ALKYL GROUPS IN Et2AlCl PROMOTED PINACOL-TYPE REARRANGEMENT

DOI: 10.1016/S0040-4039(01)81409-X

Source and publish data:

Tetrahedron Letters p. 4253 - 4256 (1984)

Update date:2022-09-26

Topics:

Authors:

Tsuchihashi, Gen-ichi

Tomooka, Katsuhiko

Suzuki, Keisuke

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Article abstract of DOI:10.1016/S0040-4039(01)81409-X

Completely stereospecific 1,2-migration of alkyl groups was achieved in Et2AlCl-promoted pinacol-type rearrangement of chiral β-mesyloxy alcohols to give optically pure α-alkyl ketones including both enantiomers of 4-methyl-3-hexanone, an alarm pheromone of ant.

Full text of DOI:10.1016/S0040-4039(01)81409-X

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