Tetrahedron Letters p. 4253 - 4256 (1984)
Update date:2022-09-26
Topics:
Tsuchihashi, Gen-ichi
Tomooka, Katsuhiko
Suzuki, Keisuke
Completely stereospecific 1,2-migration of alkyl groups was achieved in Et2AlCl-promoted pinacol-type rearrangement of chiral β-mesyloxy alcohols to give optically pure α-alkyl ketones including both enantiomers of 4-methyl-3-hexanone, an alarm pheromone of ant.
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